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Resolution of nitrogen-centered chiral tetraalkylammonium salts: application to [1,2] stevens rearrangements with N-to-C chirality transmission
http://hdl.handle.net/10191/27248
http://hdl.handle.net/10191/272480484a6f8-f5bf-49ec-b95c-9bbf7d5b93bc
名前 / ファイル | ライセンス | アクション |
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1521A.pdf (223.8 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2014-05-19 | |||||
タイトル | ||||||
タイトル | Resolution of nitrogen-centered chiral tetraalkylammonium salts: application to [1,2] stevens rearrangements with N-to-C chirality transmission | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Resolution of nitrogen-centered chiral tetraalkylammonium salts: application to [1,2] stevens rearrangements with N-to-C chirality transmission | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
その他のタイトル | ||||||
その他のタイトル | Optial resolution of nitrogen-centered chiral tetraalkylammonium salts: Application to [1,2] Stevens rearrangements with N-to-C chirality transmission | |||||
著者 |
Tayama, Eiji
× Tayama, Eiji× Otoyama, Seijun× Tanaka, Hiroyuki |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The optical resolution of N-chiral, amino acid-derived quaternary ammonium salts is demonstrated by using chiral BINOL as a complexing agent. Determination of the enantiopurities and absolute configurations of the resolved N-chiral tetraalkylammonium salts are described. The [1,2] Stevens rearrangement of N-chiral ammonium salts is shown to proceed with N-to-C chirality transmission to afford optically active 3-substituted morpholin-2-one derivatives. | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | NOTICE: this is the author’s version of a work that was accepted for publication in <Journal title>. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in PUBLICATION, [VOL20, ISSUE22, (2009-11)] DOI:10.1016/j.tetasy.2009.10.025 | |||||
書誌情報 |
Tetrahedron, asymmetry en : Tetrahedron, asymmetry 巻 20, 号 22, p. 2600-2608, 発行日 2009-11 |
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出版者 | ||||||
出版者 | Elsevier | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 09574166 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA1074621X | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1016/j.tetasy.2009.10.025 | |||||
著者版フラグ | ||||||
値 | author |