@article{oai:niigata-u.repo.nii.ac.jp:00002614, author = {Tayama, Eiji and Otoyama, Seijun and Tanaka, Hiroyuki}, issue = {22}, journal = {Tetrahedron, asymmetry, Tetrahedron, asymmetry}, month = {Nov}, note = {The optical resolution of N-chiral, amino acid-derived quaternary ammonium salts is demonstrated by using chiral BINOL as a complexing agent. Determination of the enantiopurities and absolute configurations of the resolved N-chiral tetraalkylammonium salts are described. The [1,2] Stevens rearrangement of N-chiral ammonium salts is shown to proceed with N-to-C chirality transmission to afford optically active 3-substituted morpholin-2-one derivatives., NOTICE: this is the author’s version of a work that was accepted for publication in . Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in PUBLICATION, [VOL20, ISSUE22, (2009-11)] DOI:10.1016/j.tetasy.2009.10.025}, pages = {2600--2608}, title = {Resolution of nitrogen-centered chiral tetraalkylammonium salts: application to [1,2] stevens rearrangements with N-to-C chirality transmission}, volume = {20}, year = {2009} }