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The Regio- and Stereoselective Ferrier Reaction of O-1,3-Dienyl Acetals Promoted by Organoaluminum Complexes
http://hdl.handle.net/10191/30438
http://hdl.handle.net/10191/304388c1a653f-b6ed-4f5d-82ba-4a0d23f65f5a
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
8_24_5437-5439.pdf (222.4 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2014-11-18 | |||||
| タイトル | ||||||
| タイトル | The Regio- and Stereoselective Ferrier Reaction of O-1,3-Dienyl Acetals Promoted by Organoaluminum Complexes | |||||
| タイトル | ||||||
| タイトル | The Regio- and Stereoselective Ferrier Reaction of O-1,3-Dienyl Acetals Promoted by Organoaluminum Complexes | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源 | http://purl.org/coar/resource_type/c_6501 | |||||
| タイプ | journal article | |||||
| 著者 |
Tayama, Eiji
× Tayama, Eiji× Isaka, Wataru |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | The Ferrier reaction of O-1,3-dienyl acetals promoted by organoaluminum complexes such as methylaluminum bis(2,6-di-tert-butyl-4-methylphenoxide) (MAD) is shown to proceed with a high degree of regio- and stereoselectivity to afford the corresponding alpha-alkenyl-substituted beta-alkoxy aldehydes in good yields. The mechanistic origin of the high regiocontrolling ability of MAD is elucidated. This method, coupled with the easy availability of the requisite substrates, expands the synthetic scope of the Ferrier reaction. | |||||
| 書誌情報 |
Organic Letters en : Organic Letters 巻 8, 号 24, p. 5437-5439, 発行日 2006-11 |
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| 出版者 | ||||||
| 出版者 | American chemical society | |||||
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| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 15237060 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA11347843 | |||||
| DOI | ||||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | info:doi/10.1021/ol062042j | |||||
| 著者版フラグ | ||||||
| 値 | author | |||||
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Cite as
Tayama, Eiji, Isaka, Wataru, 2006, The Regio- and Stereoselective Ferrier Reaction of O-1,3-Dienyl Acetals Promoted by Organoaluminum Complexes: American chemical society, 5437–5439 p.
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