{"created":"2021-03-01T06:05:55.980583+00:00","id":2234,"links":{},"metadata":{"_buckets":{"deposit":"cd29262d-f642-4118-ab6b-56a0da85bb2b"},"_deposit":{"id":"2234","owners":[],"pid":{"revision_id":0,"type":"depid","value":"2234"},"status":"published"},"_oai":{"id":"oai:niigata-u.repo.nii.ac.jp:00002234","sets":["176:488:489","453:454"]},"item_5_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2006-11","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"24","bibliographicPageEnd":"5439","bibliographicPageStart":"5437","bibliographicVolumeNumber":"8","bibliographic_titles":[{"bibliographic_title":"Organic Letters"},{"bibliographic_title":"Organic Letters","bibliographic_titleLang":"en"}]}]},"item_5_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The Ferrier reaction of O-1,3-dienyl acetals promoted by organoaluminum complexes such as methylaluminum bis(2,6-di-tert-butyl-4-methylphenoxide) (MAD) is shown to proceed with a high degree of regio- and stereoselectivity to afford the corresponding alpha-alkenyl-substituted beta-alkoxy aldehydes in good yields. The mechanistic origin of the high regiocontrolling ability of MAD is elucidated. This method, coupled with the easy availability of the requisite substrates, expands the synthetic scope of the Ferrier reaction.","subitem_description_type":"Abstract"}]},"item_5_publisher_7":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"American chemical society"}]},"item_5_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1021/ol062042j","subitem_relation_type_select":"DOI"}}]},"item_5_select_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_5_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11347843","subitem_source_identifier_type":"NCID"}]},"item_5_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"15237060","subitem_source_identifier_type":"ISSN"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Tayama, Eiji"}],"nameIdentifiers":[{"nameIdentifier":"7581","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Isaka, Wataru"}],"nameIdentifiers":[{"nameIdentifier":"7582","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-07-29"}],"displaytype":"detail","filename":"8_24_5437-5439.pdf","filesize":[{"value":"222.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"8_24_5437-5439.pdf","url":"https://niigata-u.repo.nii.ac.jp/record/2234/files/8_24_5437-5439.pdf"},"version_id":"61208119-a9c3-4d01-ac0e-c744aa5d4e47"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"The Regio- and Stereoselective Ferrier Reaction of O-1,3-Dienyl Acetals Promoted by Organoaluminum Complexes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"The Regio- and Stereoselective Ferrier Reaction of O-1,3-Dienyl Acetals Promoted by Organoaluminum Complexes"},{"subitem_title":"The Regio- and Stereoselective Ferrier Reaction of O-1,3-Dienyl Acetals Promoted by Organoaluminum Complexes","subitem_title_language":"en"}]},"item_type_id":"5","owner":"1","path":["454","489"],"pubdate":{"attribute_name":"公開日","attribute_value":"2014-11-18"},"publish_date":"2014-11-18","publish_status":"0","recid":"2234","relation_version_is_last":true,"title":["The Regio- and Stereoselective Ferrier Reaction of O-1,3-Dienyl Acetals Promoted by Organoaluminum Complexes"],"weko_creator_id":"1","weko_shared_id":null},"updated":"2022-12-15T03:35:05.287072+00:00"}