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Effect of temperature on HTO-Dissociation determined by Ion Exchange Resins
http://hdl.handle.net/10191/21923
http://hdl.handle.net/10191/219239d39aaa1-44dc-4d1e-a1d6-abaeceb66d8d
名前 / ファイル | ライセンス | アクション |
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15_1071-1076.pdf (56.4 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2013-04-18 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Effect of temperature on HTO-Dissociation determined by Ion Exchange Resins | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | OT-for-OH exchange reaction | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | anion-exchange resin | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | tritium | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | dissociation of tritiated water | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | apparent dissociation constant | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Kano, Naoki
× Kano, Naoki× Arai, Daisuke× Imaizumi, Hiroshi |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | In order to reveal the effect of temperature on (i) the dissociation equilibrium of tritiated water (HTO water) and (ii) the reactivity of each anion-exchange resin, the OT-for-OH exchange reaction between each anion-exchange resin and HTO water was studied within the range of 20°C to 80°C in the equilibrium state. In addition, the apparent dissociation constant (pK′) for each resin was estimated by the method of pH-titration. From the observation of the OT-for-OH exchange reaction between each of the following anion-exchange resins and HTO water, the next three items have been found: (1) in the case of acryl-type anion-exchange resin, the effect of temperature on OT-for-OH exchange reaction is larger than that on the reaction in the case of styrene-type one; (2) the radioactivity incorporated into weakly basic anion-exchange resin (OH--form) by the isotope exchange reaction is smaller than that into strongly basic one; (3) in the case of the weak-ly basic anion-exchange resin, the amount of radioactivity incorporated into Cl--form resin by the hydrolysis is larger than the amount of radioactivity incorporated into OH--form resin by the isotope exchange reaction. | |||||
言語 | en | |||||
書誌情報 |
en : Analytical Sciences 巻 15, p. 1071-1076, 発行日 1999-11 |
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出版者 | ||||||
言語 | ja | |||||
出版者 | 日本分析化学会 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0910-6340 | |||||
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収録物識別子タイプ | NCID | |||||
収録物識別子 | AA10500785 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | http://doi.org/10.2116/analsci.15.1071 | |||||
出版タイプ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
著者版フラグ | ||||||
値 | publisher |