{"created":"2021-03-01T06:05:10.954640+00:00","id":1512,"links":{},"metadata":{"_buckets":{"deposit":"72296f7a-3eb1-4790-9259-5de264156bfe"},"_deposit":{"id":"1512","owners":[],"pid":{"revision_id":0,"type":"depid","value":"1512"},"status":"published"},"_oai":{"id":"oai:niigata-u.repo.nii.ac.jp:00001512","sets":["423:424:425","453:454"]},"author_link":["4098","4099","4100"],"control_number":"1512","item_1627363077551":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_5_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1999-11","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"1076","bibliographicPageStart":"1071","bibliographicVolumeNumber":"15","bibliographic_titles":[{"bibliographic_title":"Analytical Sciences","bibliographic_titleLang":"en"}]}]},"item_5_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"In order to reveal the effect of temperature on (i) the dissociation equilibrium of tritiated water (HTO water) and (ii) the reactivity of each anion-exchange resin, the OT-for-OH exchange reaction between each anion-exchange resin and HTO water was studied within the range of 20°C to 80°C in the equilibrium state. In addition, the apparent dissociation constant (pK′) for each resin was estimated by the method of pH-titration. From the observation of the OT-for-OH exchange reaction between each of the following anion-exchange resins and HTO water, the next three items have been found: (1) in the case of acryl-type anion-exchange resin, the effect of temperature on OT-for-OH exchange reaction is larger than that on the reaction in the case of styrene-type one; (2) the radioactivity incorporated into weakly basic anion-exchange resin (OH--form) by the isotope exchange reaction is smaller than that into strongly basic one; (3) in the case of the weak-ly basic anion-exchange resin, the amount of radioactivity incorporated into Cl--form resin by the hydrolysis is larger than the amount of radioactivity incorporated into OH--form resin by the isotope exchange reaction.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_5_publisher_7":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本分析化学会","subitem_publisher_language":"ja"}]},"item_5_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://doi.org/10.2116/analsci.15.1071","subitem_relation_type_select":"DOI"}}]},"item_5_select_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"publisher"}]},"item_5_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA10500785","subitem_source_identifier_type":"NCID"}]},"item_5_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0910-6340","subitem_source_identifier_type":"ISSN"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kano, Naoki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"4098","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Arai, Daisuke","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"4099","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Imaizumi, Hiroshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"4100","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-07-29"}],"displaytype":"detail","filename":"15_1071-1076.pdf","filesize":[{"value":"56.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"15_1071-1076.pdf","url":"https://niigata-u.repo.nii.ac.jp/record/1512/files/15_1071-1076.pdf"},"version_id":"8344d27c-c42a-44ad-b0c9-d6e43b220145"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"OT-for-OH exchange reaction","subitem_subject_scheme":"Other"},{"subitem_subject":"anion-exchange resin","subitem_subject_scheme":"Other"},{"subitem_subject":"tritium","subitem_subject_scheme":"Other"},{"subitem_subject":"dissociation of tritiated water","subitem_subject_scheme":"Other"},{"subitem_subject":"apparent dissociation constant","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Effect of temperature on HTO-Dissociation determined by Ion Exchange Resins","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Effect of temperature on HTO-Dissociation determined by Ion Exchange Resins","subitem_title_language":"en"}]},"item_type_id":"5","owner":"1","path":["454","425"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2013-04-18"},"publish_date":"2013-04-18","publish_status":"0","recid":"1512","relation_version_is_last":true,"title":["Effect of temperature on HTO-Dissociation determined by Ion Exchange Resins"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-15T04:13:34.126876+00:00"}