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  1. 050 理学部
  2. 10 学術雑誌論文
  3. 10 査読済論文
  1. 0 資料タイプ別
  2. 01 学術雑誌論文

Novel biphasic reaction system of ferric chloride dissolved imidazolium hexafluorophosphate and benzotrifluoride: application to electron transfer reaction of cyclopropyl silyl ethers

http://hdl.handle.net/10191/31009
http://hdl.handle.net/10191/31009
af4c6350-b714-452d-9d99-c0a4bf2d043a
名前 / ファイル ライセンス アクション
66_1-_3447-3451.pdf 66_1-_3447-3451.pdf (470.2 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2014-12-11
タイトル
タイトル Novel biphasic reaction system of ferric chloride dissolved imidazolium hexafluorophosphate and benzotrifluoride: application to electron transfer reaction of cyclopropyl silyl ethers
タイトル
言語 en
タイトル Novel biphasic reaction system of ferric chloride dissolved imidazolium hexafluorophosphate and benzotrifluoride: application to electron transfer reaction of cyclopropyl silyl ethers
言語
言語 eng
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Tsuchida, Hiroyuki

× Tsuchida, Hiroyuki

WEKO 38082

Tsuchida, Hiroyuki

Search repository
Hasegawa, Eietsu

× Hasegawa, Eietsu

WEKO 70

Hasegawa, Eietsu

Search repository
抄録
内容記述タイプ Abstract
内容記述 Ferric chloride (FeCl3) promoted electron transfer oxidation of bicyclic cyclopropyl silyl ethers was performed in biphasic solution system of 1-butyl-3-methylimidazolium hexafluorophosphate (BmimPF6) and benzotrifluoride (BTF). The resulting chloro-substituted ring-expanded cycloalkanones were treated with an appropriate base to produce substituted cyclic enones. These two-step reactions were successfully devised to proceed in a simpler manner in which the ordinary work-up operations for the former oxidation step, such as water-quench, extraction, and evaporation, were omitted; imidazole was found to be the most suitable base for the latter elimination step.
書誌情報 Tetrahedron
en : Tetrahedron

巻 66, 号 19, p. 3447-3451, 発行日 2010-05
出版者
出版者 Elsevier
ISSN
収録物識別子タイプ ISSN
収録物識別子 00404020
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA00861787
DOI
識別子タイプ DOI
関連識別子 info:doi/10.1016/j.tet.2010.03.029
権利
権利情報 Copyright(C)2010 Elsevier
著者版フラグ
値 author
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