ログイン
言語:

WEKO3

  • トップ
  • ランキング
To
lat lon distance
To

Field does not validate



インデックスリンク

インデックスツリー

メールアドレスを入力してください。

WEKO

One fine body…

WEKO

One fine body…

アイテム

{"_buckets": {"deposit": "f2aa1e10-09cd-4b86-9b90-d8066418f52c"}, "_deposit": {"id": "2589", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "2589"}, "status": "published"}, "_oai": {"id": "oai:niigata-u.repo.nii.ac.jp:00002589", "sets": ["454", "489"]}, "item_5_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2013-01", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "1", "bibliographicPageEnd": "267", "bibliographicPageStart": "247", "bibliographicVolumeNumber": "39", "bibliographic_titles": [{"bibliographic_title": "Research on Chemical Intermediates"}, {"bibliographic_title": "Research on Chemical Intermediates", "bibliographic_titleLang": "en"}]}]}, "item_5_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Photoinduced electron-transfer reaction of α-bromomethyl-substituted benzocyclic β-keto esters with tertiary amines was investigated. Debrominated β-keto esters and ring-expanded γ-keto esters were obtained as major products. On the basis of mechanistic experiments it was concluded that these products are formed via a reaction sequence of selective carbon–bromine bond cleavage and subsequent competitive hydrogen abstraction and Dowd–Beckwith ring-expansion of the resulting primary alkyl radicals. The characteristic product distribution observed for the type of amine used is rationalized on the basis of selective reaction pathways of generated radical intermediates that depend on the nature of the amine radical cations.", "subitem_description_type": "Abstract"}]}, "item_5_publisher_7": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Springer Verlag"}]}, "item_5_relation_14": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "info:doi/10.1007/s11164-012-0646-2", "subitem_relation_type_select": "DOI"}}]}, "item_5_rights_15": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "Copyright(C)2013 Springer Verlag"}]}, "item_5_select_19": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_5_source_id_11": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA10679655", "subitem_source_identifier_type": "NCID"}]}, "item_5_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "09226168", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Hasegawa, Eietsu"}], "nameIdentifiers": [{"nameIdentifier": "70", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tosaka, Emi"}], "nameIdentifiers": [{"nameIdentifier": "37963", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yoneoka, Akira"}], "nameIdentifiers": [{"nameIdentifier": "37964", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tamura, Yukinobu"}], "nameIdentifiers": [{"nameIdentifier": "37965", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Takizawa, Shin-ya"}], "nameIdentifiers": [{"nameIdentifier": "37966", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tomura, Masaaki"}], "nameIdentifiers": [{"nameIdentifier": "37967", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yamashita, Yoshiro"}], "nameIdentifiers": [{"nameIdentifier": "37968", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-07-29"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "39_1_247-267.pdf", "filesize": [{"value": "948.9 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 948900.0, "url": {"label": "39_1_247-267.pdf", "url": "https://niigata-u.repo.nii.ac.jp/record/2589/files/39_1_247-267.pdf"}, "version_id": "6a3dabc4-7bc7-4a53-ac61-17c82b9a68c0"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "Photoinduced electron-transfer", "subitem_subject_scheme": "Other"}, {"subitem_subject": "α-Bromomethyl-substituted benzocyclic β-keto esters", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Tertiary amines", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Radical ions", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Dowd–Beckwith ring-expansion", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Photoinduced electron-transfer reaction of α-bromomethyl-substituted benzocyclic β-keto esters with amines: selective reaction pathways depending on the nature of the amine radical cations", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Photoinduced electron-transfer reaction of α-bromomethyl-substituted benzocyclic β-keto esters with amines: selective reaction pathways depending on the nature of the amine radical cations"}, {"subitem_title": "Photoinduced electron-transfer reaction of α-bromomethyl-substituted benzocyclic β-keto esters with amines: selective reaction pathways depending on the nature of the amine radical cations", "subitem_title_language": "en"}]}, "item_type_id": "5", "owner": "1", "path": ["454", "489"], "permalink_uri": "http://hdl.handle.net/10191/31006", "pubdate": {"attribute_name": "公開日", "attribute_value": "2014-12-11"}, "publish_date": "2014-12-11", "publish_status": "0", "recid": "2589", "relation": {}, "relation_version_is_last": true, "title": ["Photoinduced electron-transfer reaction of α-bromomethyl-substituted benzocyclic β-keto esters with amines: selective reaction pathways depending on the nature of the amine radical cations"], "weko_shared_id": null}
  1. 050 理学部
  2. 10 学術雑誌論文
  3. 10 査読済論文
  1. 0 資料タイプ別
  2. 01 学術雑誌論文

Photoinduced electron-transfer reaction of α-bromomethyl-substituted benzocyclic β-keto esters with amines: selective reaction pathways depending on the nature of the amine radical cations

http://hdl.handle.net/10191/31006
http://hdl.handle.net/10191/31006
0e8c6df8-0cbf-4479-a5a7-bf47663ea6a5
名前 / ファイル ライセンス アクション
39_1_247-267.pdf 39_1_247-267.pdf (948.9 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2014-12-11
タイトル
タイトル Photoinduced electron-transfer reaction of α-bromomethyl-substituted benzocyclic β-keto esters with amines: selective reaction pathways depending on the nature of the amine radical cations
タイトル
言語 en
タイトル Photoinduced electron-transfer reaction of α-bromomethyl-substituted benzocyclic β-keto esters with amines: selective reaction pathways depending on the nature of the amine radical cations
言語
言語 eng
キーワード
主題Scheme Other
主題 Photoinduced electron-transfer
キーワード
主題Scheme Other
主題 α-Bromomethyl-substituted benzocyclic β-keto esters
キーワード
主題Scheme Other
主題 Tertiary amines
キーワード
主題Scheme Other
主題 Radical ions
キーワード
主題Scheme Other
主題 Dowd–Beckwith ring-expansion
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Hasegawa, Eietsu

× Hasegawa, Eietsu

WEKO 70

Hasegawa, Eietsu

Search repository
Tosaka, Emi

× Tosaka, Emi

WEKO 37963

Tosaka, Emi

Search repository
Yoneoka, Akira

× Yoneoka, Akira

WEKO 37964

Yoneoka, Akira

Search repository
Tamura, Yukinobu

× Tamura, Yukinobu

WEKO 37965

Tamura, Yukinobu

Search repository
Takizawa, Shin-ya

× Takizawa, Shin-ya

WEKO 37966

Takizawa, Shin-ya

Search repository
Tomura, Masaaki

× Tomura, Masaaki

WEKO 37967

Tomura, Masaaki

Search repository
Yamashita, Yoshiro

× Yamashita, Yoshiro

WEKO 37968

Yamashita, Yoshiro

Search repository
抄録
内容記述タイプ Abstract
内容記述 Photoinduced electron-transfer reaction of α-bromomethyl-substituted benzocyclic β-keto esters with tertiary amines was investigated. Debrominated β-keto esters and ring-expanded γ-keto esters were obtained as major products. On the basis of mechanistic experiments it was concluded that these products are formed via a reaction sequence of selective carbon–bromine bond cleavage and subsequent competitive hydrogen abstraction and Dowd–Beckwith ring-expansion of the resulting primary alkyl radicals. The characteristic product distribution observed for the type of amine used is rationalized on the basis of selective reaction pathways of generated radical intermediates that depend on the nature of the amine radical cations.
書誌情報 Research on Chemical Intermediates
en : Research on Chemical Intermediates

巻 39, 号 1, p. 247-267, 発行日 2013-01
出版者
出版者 Springer Verlag
ISSN
収録物識別子タイプ ISSN
収録物識別子 09226168
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA10679655
DOI
識別子タイプ DOI
関連識別子 info:doi/10.1007/s11164-012-0646-2
権利
権利情報 Copyright(C)2013 Springer Verlag
著者版フラグ
値 author
戻る
0
views
See details
Views

Versions

Ver.1 2021-03-01 20:29:59.161768
Show All versions

Share

Mendeley Twitter Facebook Print Addthis

Cite as

エクスポート

OAI-PMH
  • OAI-PMH JPCOAR
  • OAI-PMH DublinCore
  • OAI-PMH DDI
Other Formats
  • JSON
  • BIBTEX

Confirm


Powered by WEKO3


Powered by WEKO3