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  1. 050 理学部
  2. 10 学術雑誌論文
  3. 10 査読済論文
  1. 0 資料タイプ別
  2. 01 学術雑誌論文

He*(2 3S) penning ionization of H2S. II. Formation of the SH+(A 3Π) and H2S+(Ã 2A1) ions

http://hdl.handle.net/10191/6278
http://hdl.handle.net/10191/6278
7a375149-612b-422c-89b6-56a3616ab104
名前 / ファイル ライセンス アクション
13_0007.pdf 13_0007.pdf (976.2 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2008-04-23
タイトル
タイトル He*(2 3S) penning ionization of H2S. II. Formation of the SH+(A 3Π) and H2S+(Ã 2A1) ions
タイトル
言語 en
タイトル He*(2 3S) penning ionization of H2S. II. Formation of the SH+(A 3Π) and H2S+(Ã 2A1) ions
言語
言語 eng
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Tokue, Ikuo

× Tokue, Ikuo

WEKO 6649

Tokue, Ikuo

Search repository
Yamasaki, Katsuyoshi

× Yamasaki, Katsuyoshi

WEKO 6650

Yamasaki, Katsuyoshi

Search repository
Nanbu, Shinkoh

× Nanbu, Shinkoh

WEKO 6651

Nanbu, Shinkoh

Search repository
著者別名
識別子 6652
識別子Scheme WEKO
姓名 徳江, 郁雄
抄録
内容記述タイプ Abstract
内容記述 Emissions in the 200–750 nm region produced by the collision of He*(2 3S) with H2S were studied under single-collision conditions. The hydrogen Balmer lines and the SH+(A 3Π–X 3s∑–) and H2S+(à 2A1–X2B1) bands were assigned. The total emission cross section (σem) was evaluated to be (1.7±0.3)×10–20 m2 at a collision energy of 150 meV. The ems of the SH+(A–X) and H2S+(ÖX) bands decreased with increase in the collision energy in the 115–200 meV range, indicating that attractive forces are effective for the incident channels with regard to the formation of these species. The rotational distribution of SH+(A 3Π, ν‘= 0) is represented by a Boltzmann temperature of 870±80 K. The H2S+(à 2A1–X2B1) emission, which was assigned for the first time in the Penning ionization of H2S, primarily consists of the bending progressions. The internal populations of H2S+(Ã) were analyzed using the vibrational energies and Einstein's A coefficients calculated in this study. The details of the calculation and derived spectroscopic constants are reported in the accompanying paper, Paper I. The populations obtained for the bending vibration (ν’2) of H2S+(Ã) show an inverted distribution with a peak at ν’2= 3. This distribution is shifted lower compared that with a peak at ν’2=4–5 observed by He*(2 3S) Penning ionization electron spectroscopy and that with a peak at ν’2=6–7 predicted by the theoretical Franck–Condon factors for the H2S(X)–H2S+(Ã) ionization. The origin of the difference is discussed concerning the formation mechanism of H2S+(à 2A1).
書誌情報 Journal of Chemical Physics
en : Journal of Chemical Physics

巻 119, 号 12, p. 5882-5888, 発行日 2003
出版者
出版者 American Institute of Physics
ISSN
収録物識別子タイプ ISSN
収録物識別子 00219606
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA00694991
DOI
識別子タイプ DOI
関連識別子 info:doi/10.1063/1.1602064
権利
権利情報 ©2003 American Institute of Physics
著者版フラグ
値 publisher
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