{"_buckets": {"deposit": "fbcab538-b35b-47ac-9cbb-ce39a1f1e3db"}, "_deposit": {"id": "2017", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "2017"}, "status": "published"}, "_oai": {"id": "oai:niigata-u.repo.nii.ac.jp:00002017"}, "item_5_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2003", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "12", "bibliographicPageEnd": "5888", "bibliographicPageStart": "5882", "bibliographicVolumeNumber": "119", "bibliographic_titles": [{"bibliographic_title": "Journal of Chemical Physics"}, {"bibliographic_title": "Journal of Chemical Physics", "bibliographic_titleLang": "en"}]}]}, "item_5_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Emissions in the 200\u2013750 nm region produced by the collision of He*(2 3S) with H2S were studied under single-collision conditions. The hydrogen Balmer lines and the SH+(A 3\u03a0\u2013X 3s\u2211\u2013) and H2S+(\u00c3 2A1\u2013X2B1) bands were assigned. The total emission cross section (\u03c3em) was evaluated to be (1.7\u00b10.3)\u00d710\u201320 m2 at a collision energy of 150 meV. The  ems of the SH+(A\u2013X) and H2S+(\u00c3\u2013X) bands decreased with increase in the collision energy in the 115\u2013200 meV range, indicating that attractive forces are effective for the incident channels with regard to the formation of these species. The rotational distribution of SH+(A 3\u03a0, \u03bd\u2018= 0) is represented by a Boltzmann temperature of 870\u00b180 K. The H2S+(\u00c3 2A1\u2013X2B1) emission, which was assigned for the first time in the Penning ionization of H2S, primarily consists of the bending progressions. The internal populations of H2S+(\u00c3) were analyzed using the vibrational energies and Einstein\u0027s A coefficients calculated in this study. The details of the calculation and derived spectroscopic constants are reported in the accompanying paper, Paper I. The populations obtained for the bending vibration (\u03bd\u20192) of H2S+(\u00c3) show an inverted distribution with a peak at \u03bd\u20192= 3. This distribution is shifted lower compared that with a peak at \u03bd\u20192=4\u20135 observed by He*(2 3S) Penning ionization electron spectroscopy and that with a peak at \u03bd\u20192=6\u20137 predicted by the theoretical Franck\u2013Condon factors for the H2S(X)\u2013H2S+(\u00c3) ionization. The origin of the difference is discussed concerning the formation mechanism of H2S+(\u00c3 2A1).", "subitem_description_type": "Abstract"}]}, "item_5_full_name_3": {"attribute_name": "\u8457\u8005\u5225\u540d", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "6652", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "\u5fb3\u6c5f, \u90c1\u96c4"}]}]}, "item_5_publisher_7": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "American Institute of Physics"}]}, "item_5_relation_14": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "info:doi/10.1063/1.1602064", "subitem_relation_type_select": "DOI"}}]}, "item_5_rights_15": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\u00a92003 American Institute of Physics"}]}, "item_5_select_19": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_5_source_id_11": {"attribute_name": "\u66f8\u8a8c\u30ec\u30b3\u30fc\u30c9ID", "attribute_value_mlt": [{"subitem_source_identifier": "AA00694991", "subitem_source_identifier_type": "NCID"}]}, "item_5_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "00219606", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Tokue, Ikuo"}], "nameIdentifiers": [{"nameIdentifier": "6649", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yamasaki, Katsuyoshi"}], "nameIdentifiers": [{"nameIdentifier": "6650", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nanbu, Shinkoh"}], "nameIdentifiers": [{"nameIdentifier": "6651", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-07-29"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "13_0007.pdf", "filesize": [{"value": "976.2 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 976200.0, "url": {"label": "13_0007.pdf", "url": "https://niigata-u.repo.nii.ac.jp/record/2017/files/13_0007.pdf"}, "version_id": "ec7a407b-e265-4313-bdc0-20860599dfea"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "He*(2 3S) penning ionization of H2S. II. Formation of the SH+(A 3\u03a0) and H2S+(\u00c3 2A1) ions", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "He*(2 3S) penning ionization of H2S. II. Formation of the SH+(A 3\u03a0) and H2S+(\u00c3 2A1) ions"}, {"subitem_title": "He*(2 3S) penning ionization of H2S. II. Formation of the SH+(A 3\u03a0) and H2S+(\u00c3 2A1) ions", "subitem_title_language": "en"}]}, "item_type_id": "5", "owner": "1", "path": ["453/454", "176/488/489"], "permalink_uri": "http://hdl.handle.net/10191/6278", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2008-04-23"}, "publish_date": "2008-04-23", "publish_status": "0", "recid": "2017", "relation": {}, "relation_version_is_last": true, "title": ["He*(2 3S) penning ionization of H2S. II. Formation of the SH+(A 3\u03a0) and H2S+(\u00c3 2A1) ions"], "weko_shared_id": null}