{"_buckets": {"deposit": "82fb0b29-80e9-4154-8040-69fd36c4f810"}, "_deposit": {"id": "2000401", "owners": [1], "pid": {"revision_id": 0, "type": "depid", "value": "2000401"}, "status": "published"}, "_oai": {"id": "oai:niigata-u.repo.nii.ac.jp:02000401", "sets": ["456", "1650509650066"]}, "author_link": [], "item_1627361970403": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_7_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2022-02", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "2", "bibliographicPageEnd": "110", "bibliographicPageStart": "91", "bibliographicVolumeNumber": "14", "bibliographic_titles": [{"bibliographic_title": "新潟大学教育学部研究紀要 自然科学編", "bibliographic_titleLang": "ja"}]}]}, "item_7_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "The photo-electron transfer oxygenation reaction catalyzed by triphenylpyrylium tetrafluoroborate (TPPBF_4) has been known to be an effective method for the synthesis of antimalarial 1,5-diaryl-6,7-dioxabicyclo[3.2.2]nonanes. In this paper the reaction was modified for teaching material of undergraduate chemical experiments without using expensive equipments. Various 2,6-diarylhepta-1,6-dienes 4a-c, 4e were efficiently oxygenated by TPPBF_4-sensitized photo-electron transfer reaction using sunlight to afford the corresponding antimalarial 1,5-diaryl-6,7-dioxabicyclo[3.2.2]nonanes 5a-c, 5e.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_7_publisher_7": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "新潟大学教育学部", "subitem_publisher_language": "ja"}]}, "item_7_source_id_11": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA12358288", "subitem_source_identifier_type": "NCID"}]}, "item_7_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1883-3845", "subitem_source_identifier_type": "PISSN"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "早川, 潤", "creatorNameLang": "ja"}, {"creatorName": "Hayakawa, Jun", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "鎌田, 正喜", "creatorNameLang": "ja"}, {"creatorName": "Kamata, Masaki", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "渡辺, 輝", "creatorNameLang": "ja"}, {"creatorName": "Watanabe, Hikaru", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "金, 惠淑", "creatorNameLang": "ja"}, {"creatorName": "Kim, Hye-Sook", "creatorNameLang": "en"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_access", "date": [{"dateType": "Available", "dateValue": "2022-04-21"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "14(2)_91-110.pdf", "filesize": [{"value": "2.01MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": "2.01MB", "url": {"objectType": "fulltext", "url": "https://niigata-u.repo.nii.ac.jp/record/2000401/files/14(2)_91-110.pdf"}, "version_id": "141e5513-8363-4c5b-b549-43fd31a2e00f"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "photochemical reaction using sunlight", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "photochemical reaction for experimental teaching material", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "single-electron transfer", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "photo-oxygenation", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "photo-electron transfer reaction", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "triphenylpyrylium tetrafluoroborate", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "2,6-diarylhepta-1,6-dienes", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "1,5-diaryl-6,7-dioxabicyclo[3.2.2]-nonanes", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "antimalarial cyclic peroxides", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "antimalarials", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "光化学反応の教材化(5) : 太陽光を活用する抗マラリア活性1,5-ジアリール-6,7-ジオキサビシクロ[3.2.2]ノナン類の合成", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "光化学反応の教材化(5) : 太陽光を活用する抗マラリア活性1,5-ジアリール-6,7-ジオキサビシクロ[3.2.2]ノナン類の合成", "subitem_title_language": "ja"}, {"subitem_title": "Photochemical reaction for experimental teaching material(5) : Applications of sunlight-induced triphenylpyrylium salt-sensitized electron transfer photo-oxygenation reactions to the synthesis of antimalarial 1,5-diaryl-6,7-dioxabicyclo[3.2.2]nonanes", "subitem_title_language": "en"}]}, "item_type_id": "7", "owner": "1", "path": ["456", "1650509650066"], "permalink_uri": "http://hdl.handle.net/10191/0002000401", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2022-04-21"}, "publish_date": "2022-04-21", "publish_status": "0", "recid": "2000401", "relation": {}, "relation_version_is_last": true, "title": ["光化学反応の教材化(5) : 太陽光を活用する抗マラリア活性1,5-ジアリール-6,7-ジオキサビシクロ[3.2.2]ノナン類の合成"], "weko_shared_id": -1}