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Copper(II)-salt-promoted oxidative ring-opening reactions of bicyclic cyclopropanol derivatives via radical pathways
http://hdl.handle.net/10191/30434
http://hdl.handle.net/10191/30434aae5bd13-62d1-4502-9799-d4ed36b9d35b
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
9_1397-1406.pdf (460.5 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2014-11-18 | |||||
| タイトル | ||||||
| タイトル | Copper(II)-salt-promoted oxidative ring-opening reactions of bicyclic cyclopropanol derivatives via radical pathways | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | copper(II) salt | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | cyclopropanol | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | electron transfer | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | free radical | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | radical ion probe | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Hasegawa, Eietsu
× Hasegawa, Eietsu× Tateyama, Minami× Nagumo, Ryosuke× Tayama, Eiji× Iwamoto, Hajime |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Copper(II)-salt-promoted oxidative ring-opening reactions of bicyclic cyclopropanol derivatives were investigated. The regioselectivities of these processes were found to be influenced by the structure of cyclopropanols as well as the counter anion of the copper(II) salts. A mechanism involving rearrangement reactions of radical intermediates and their competitive trapping by copper ions is proposed. | |||||
| 書誌情報 |
Beilstein Journal of Organic Chemistry en : Beilstein Journal of Organic Chemistry 巻 9, p. 1397-1406, 発行日 2013-07 |
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| 出版者 | ||||||
| 出版者 | Beilstein Institut | |||||
| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 18605397 | |||||
| DOI | ||||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | info:doi/10.3762/bjoc.9.156 | |||||
| 著者版フラグ | ||||||
| 値 | publisher | |||||
