@misc{oai:niigata-u.repo.nii.ac.jp:00005318,
 author = {Li, Jun},
 month = {Sep},
 note = {Simultaneous polymerization of the two different types of polymerizations, i. e., addition polymerization and polyaddition of one new monomer(l) having one terminal triple bond and two Si-H groups has been achieved by using [Rh(nbd)C1]2 / various amines. To our knowledge, this is the first example of such simultaneous polymerization of one monomer. In addition, the ratio of the two polymerizations could be controlled by changing amine cocatalyst. By this polymerization method, one-pot synthesis of poly(hyperbranched acetylene-type macromonomer) from 1 was realized. In addition monomer 2, 3, 4 (see chart 1) having one terminal triple bond and one or two Si-H groups have been polymerized by [Rh(nbd)C1]2 / various amines. To the best of our knowledge, this is the first synthesis of such complex polymers. Membranes from the poly(hyperbranched acetylene-type macromonomer) had both the advantages of poly(phenylacetylene)s and poly(dendron). Some of them showed the highest performance as oxygen or carbon dioxide permselective membranes among the all membranes reported. In summary, a new complex polymer, poly(hyperbranched acetylene-type macromonomer) showing good performance as gas separation membranes were synthesized very easily by the one-pot simultaneous polymerization method., 学位の種類: 博士（工学）. 報告番号: 甲第3704号. 学位記番号: 新大院博（工）甲第387号. 学位授与年月日: 平成24年9月20日, 新大院博（工）甲第387号},
 title = {One-pot synthesis of poly (hyperbranched acetylene-type macromonomer) by simultaneous polymerization of two different modes of polymerizations for gas permselective membranes},
 year = {2012}
}