{"created":"2021-03-01T06:39:52.011090+00:00","id":33436,"links":{},"metadata":{"_buckets":{"deposit":"073eabbf-594d-4fbf-97bf-df01c3673e05"},"_deposit":{"id":"33436","owners":[],"pid":{"revision_id":0,"type":"depid","value":"33436"},"status":"published"},"_oai":{"id":"oai:niigata-u.repo.nii.ac.jp:00033436","sets":["154:155:1387:1934","453:456"]},"item_7_alternative_title_1":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Photochemical reaction for experimental teaching material (4) : applications of triphenylpyrylium salt-sensitized electron-transfer photo-oxygenation reactions to the green deprotection of 1,3-dithianes"}]},"item_7_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-10","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"55","bibliographicPageStart":"37","bibliographicVolumeNumber":"11","bibliographic_titles":[{"bibliographic_title":"新潟大学教育学部研究紀要 自然科学編"},{"bibliographic_title":"新潟大学教育学部研究紀要 自然科学編","bibliographic_titleLang":"en"}]}]},"item_7_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The photo-electron transfer (PET)-promoted oxygenation reaction catalyzed by 2,4,6-triphenylpyrylium perchlorate (TPPClO_4) was found to be an effective and green method for the deprotection of various 1,3-dithianes. In this paper the green deprotection reaction was modified for teaching material of undergraduate chemical experiments without using expensive equipments. Various 1,3-dithianes were efficiently deprotected to afford the corresponding carbonyl compounds by using sunlight and TPPClO_4 as part of green chemistry.","subitem_description_type":"Abstract"}]},"item_7_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"47","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Kamata, Masaki"}]},{"nameIdentifiers":[{"nameIdentifier":"176294","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Hayakawa, Jun"}]}]},"item_7_publisher_7":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"新潟大学教育学部"}]},"item_7_select_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"publisher"}]},"item_7_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA12358288","subitem_source_identifier_type":"NCID"}]},"item_7_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"18833845","subitem_source_identifier_type":"ISSN"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"鎌田, 正喜"}],"nameIdentifiers":[{"nameIdentifier":"47","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"早川, 潤"}],"nameIdentifiers":[{"nameIdentifier":"176292","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-09-19"}],"displaytype":"detail","filename":"11(1)_37-55.pdf","filesize":[{"value":"2.2 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"11(1)_37-55.pdf","url":"https://niigata-u.repo.nii.ac.jp/record/33436/files/11(1)_37-55.pdf"},"version_id":"57c16413-c012-4845-8688-72bbe959e92c"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"teaching material for chemical experiments","subitem_subject_scheme":"Other"},{"subitem_subject":"single-electron transfer","subitem_subject_scheme":"Other"},{"subitem_subject":"photo-oxygenation","subitem_subject_scheme":"Other"},{"subitem_subject":"photo-electron transfer reaction","subitem_subject_scheme":"Other"},{"subitem_subject":"triphenylpyrylium perchlorate","subitem_subject_scheme":"Other"},{"subitem_subject":"1,3-dithianes","subitem_subject_scheme":"Other"},{"subitem_subject":"deprotection","subitem_subject_scheme":"Other"},{"subitem_subject":"sunlight","subitem_subject_scheme":"Other"},{"subitem_subject":"sunlight induced reaction","subitem_subject_scheme":"Other"},{"subitem_subject":"utilization of sunlight for chemical experiment","subitem_subject_scheme":"Other"},{"subitem_subject":"green chemistry","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"光化学実験の教材化 (4) : ピリリウム塩増感電子移動光酸素化による1,3-ジチアン類のグリーンな脱保護反応","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"光化学実験の教材化 (4) : ピリリウム塩増感電子移動光酸素化による1,3-ジチアン類のグリーンな脱保護反応"}]},"item_type_id":"7","owner":"1","path":["456","1934"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-11-14"},"publish_date":"2018-11-14","publish_status":"0","recid":"33436","relation_version_is_last":true,"title":["光化学実験の教材化 (4) : ピリリウム塩増感電子移動光酸素化による1,3-ジチアン類のグリーンな脱保護反応"],"weko_creator_id":"1","weko_shared_id":2},"updated":"2022-12-15T04:09:24.192532+00:00"}