{"created":"2021-03-01T06:32:03.263815+00:00","id":26464,"links":{},"metadata":{"_buckets":{"deposit":"8f2992d6-2132-4dad-8efc-7f20812510cb"},"_deposit":{"id":"26464","owners":[],"pid":{"revision_id":0,"type":"depid","value":"26464"},"status":"published"},"_oai":{"id":"oai:niigata-u.repo.nii.ac.jp:00026464","sets":["154:155:1387:1390","453:456"]},"item_7_alternative_title_1":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Photochemical reaction for experimental teaching material (3): Applications of sunlight-induced triphenylpyrylium salt-sensitized electron-transfer photo-oxygenation reactions to the deprotection of tosylhydrazones"}]},"item_7_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-03","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"106","bibliographicPageStart":"91","bibliographicVolumeNumber":"9","bibliographic_titles":[{"bibliographic_title":"新潟大学教育学部研究紀要 自然科学編"},{"bibliographic_title":"新潟大学教育学部研究紀要 自然科学編","bibliographic_titleLang":"en"}]}]},"item_7_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The photo-electron transfer (PET)-promoted oxygenation reaction catalyzed by triphenylpyrylium perchlorate (TPPClO4) was found to be an effective method for the deprotection of tosylhydrazones. In this paper the above mentioned reaction was modified for teaching material of undergraduate chemical experiments without using expensive equipments. Various tosylhydrazones were efficiently deprotected to afford the corresponding ketones and aldehydes using TPPClO4 and sunlight.","subitem_description_type":"Abstract"}]},"item_7_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"47","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Kamata, Masaki"}]},{"nameIdentifiers":[{"nameIdentifier":"156016","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Hayakawa, Jun"}]}]},"item_7_publisher_7":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"新潟大学教育学部"}]},"item_7_select_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"publisher"}]},"item_7_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA12358288","subitem_source_identifier_type":"NCID"}]},"item_7_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"18833845","subitem_source_identifier_type":"ISSN"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"鎌田, 正喜"}],"nameIdentifiers":[{"nameIdentifier":"47","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"早川, 潤"}],"nameIdentifiers":[{"nameIdentifier":"156014","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-08-19"}],"displaytype":"detail","filename":"9(2)_91-106.pdf","filesize":[{"value":"1.3 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"9(2)_91-106.pdf","url":"https://niigata-u.repo.nii.ac.jp/record/26464/files/9(2)_91-106.pdf"},"version_id":"40276139-a224-42a7-a196-8bcffffc8a3a"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"teaching material for chemical experiments","subitem_subject_scheme":"Other"},{"subitem_subject":"single-electron transfer","subitem_subject_scheme":"Other"},{"subitem_subject":"photo-oxygenation","subitem_subject_scheme":"Other"},{"subitem_subject":"photoelectron transfer reaction","subitem_subject_scheme":"Other"},{"subitem_subject":"triphenylpyrylium perchlorate","subitem_subject_scheme":"Other"},{"subitem_subject":"tosylhydrazone","subitem_subject_scheme":"Other"},{"subitem_subject":"deprotection","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"光化学実験の教材化（３） : 太陽光を利用するピリリウム塩増感電子移動光酸素化反応：トシルヒドラゾン類の脱保護反応","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"光化学実験の教材化（３） : 太陽光を利用するピリリウム塩増感電子移動光酸素化反応：トシルヒドラゾン類の脱保護反応"}]},"item_type_id":"7","owner":"1","path":["456","1390"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-11-30"},"publish_date":"2017-11-30","publish_status":"0","recid":"26464","relation_version_is_last":true,"title":["光化学実験の教材化（３） : 太陽光を利用するピリリウム塩増感電子移動光酸素化反応：トシルヒドラゾン類の脱保護反応"],"weko_creator_id":"1","weko_shared_id":2},"updated":"2022-12-15T03:56:15.081596+00:00"}