{"created":"2021-03-01T06:06:19.332153+00:00","id":2601,"links":{},"metadata":{"_buckets":{"deposit":"66cf6b0a-8a64-47e7-a21f-f5d1dd9dc0b9"},"_deposit":{"id":"2601","owners":[],"pid":{"revision_id":0,"type":"depid","value":"2601"},"status":"published"},"_oai":{"id":"oai:niigata-u.repo.nii.ac.jp:00002601"},"item_5_biblio_info_6":{"attribute_name":"\u66f8\u8a8c\u60c5\u5831","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2006-03","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"6","bibliographicPageEnd":"852","bibliographicPageStart":"849","bibliographicVolumeNumber":"2006","bibliographic_titles":[{"bibliographic_title":"Synlett"},{"bibliographic_title":"Synlett","bibliographic_titleLang":"en"}]}]},"item_5_description_4":{"attribute_name":"\u6284\u9332","attribute_value_mlt":[{"subitem_description":"Treatment of 1-alkoxy-4-methoxy-(2Z)-alkenes or 1-sil-oxy-4-methoxy-(2Z)-alkenes with n-butyllithium in diethyl ether is shown to afford the corresponding (1Z,3E)-dienyl, alkyl or silyl ethers, respectively, in high stereoselectivity via a facile 1,4-elimination. The scope and the regio- and stereochemical features of the synthetic method are described.","subitem_description_type":"Abstract"}]},"item_5_publisher_7":{"attribute_name":"\u51fa\u7248\u8005","attribute_value_mlt":[{"subitem_publisher":"Georg Thieme Verlag"}]},"item_5_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1055/s-2006-939053","subitem_relation_type_select":"DOI"}}]},"item_5_rights_15":{"attribute_name":"\u6a29\u5229","attribute_value_mlt":[{"subitem_rights":"Copyright(C) 2006 Georg Thieme Verlag"}]},"item_5_select_19":{"attribute_name":"\u8457\u8005\u7248\u30d5\u30e9\u30b0","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_5_source_id_11":{"attribute_name":"\u66f8\u8a8c\u30ec\u30b3\u30fc\u30c9ID","attribute_value_mlt":[{"subitem_source_identifier":"AA10731110","subitem_source_identifier_type":"NCID"}]},"item_5_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"09365214","subitem_source_identifier_type":"ISSN"}]},"item_creator":{"attribute_name":"\u8457\u8005","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Tayama, Eiji"}],"nameIdentifiers":[{"nameIdentifier":"38067","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sugai, Sayaka"}],"nameIdentifiers":[{"nameIdentifier":"38068","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"\u30d5\u30a1\u30a4\u30eb\u60c5\u5831","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-07-29"}],"displaytype":"detail","filename":"1531.pdf","filesize":[{"value":"114.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"1531.pdf","url":"https://niigata-u.repo.nii.ac.jp/record/2601/files/1531.pdf"},"version_id":"4fe53748-b1be-4d28-9a10-6a6fa7145b4a"}]},"item_keyword":{"attribute_name":"\u30ad\u30fc\u30ef\u30fc\u30c9","attribute_value_mlt":[{"subitem_subject":"1,4-eliminations","subitem_subject_scheme":"Other"},{"subitem_subject":"dienyl ethers","subitem_subject_scheme":"Other"},{"subitem_subject":"dienyl acetals","subitem_subject_scheme":"Other"},{"subitem_subject":"stereoselective synthesis","subitem_subject_scheme":"Other"},{"subitem_subject":"precoordinations","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"\u8a00\u8a9e","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"\u8cc7\u6e90\u30bf\u30a4\u30d7","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"A Facile Method for the Stereoselective Preparation of (1Z, 3E)-Dienyl Ethers via 1,4-Elimination of 1,4-Dialkoxy-(2Z)-alkenes with n-Butyllithium","item_titles":{"attribute_name":"\u30bf\u30a4\u30c8\u30eb","attribute_value_mlt":[{"subitem_title":"A Facile Method for the Stereoselective Preparation of (1Z, 3E)-Dienyl Ethers via 1,4-Elimination of 1,4-Dialkoxy-(2Z)-alkenes with n-Butyllithium"},{"subitem_title":"A Facile Method for the Stereoselective Preparation of (1Z, 3E)-Dienyl Ethers via 1,4-Elimination of 1,4-Dialkoxy-(2Z)-alkenes with n-Butyllithium","subitem_title_language":"en"}]},"item_type_id":"5","owner":"1","path":["453/454","176/488/489"],"pubdate":{"attribute_name":"\u516c\u958b\u65e5","attribute_value":"2014-04-22"},"publish_date":"2014-04-22","publish_status":"0","recid":"2601","relation_version_is_last":true,"title":["A Facile Method for the Stereoselective Preparation of (1Z, 3E)-Dienyl Ethers via 1,4-Elimination of 1,4-Dialkoxy-(2Z)-alkenes with n-Butyllithium"],"weko_creator_id":"1","weko_shared_id":null},"updated":"2021-03-01T20:29:36.965339+00:00"}