{"created":"2021-03-01T06:06:12.963604+00:00","id":2502,"links":{},"metadata":{"_buckets":{"deposit":"c7ec37a8-7f11-4637-a07e-4cde9e96b88a"},"_deposit":{"id":"2502","owners":[],"pid":{"revision_id":0,"type":"depid","value":"2502"},"status":"published"},"_oai":{"id":"oai:niigata-u.repo.nii.ac.jp:00002502","sets":["176:488:489","453:454"]},"item_5_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2009-07","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"014201-10","bibliographicPageStart":"014201-1","bibliographicVolumeNumber":"80","bibliographic_titles":[{"bibliographic_title":"Physical review. Third series. B, Condensed matter and materials physics"},{"bibliographic_title":"Physical review. Third series. B, Condensed matter and materials physics","bibliographic_titleLang":"en"}]}]},"item_5_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The reverse Monte Carlo and Voronoi-Delaunay analyses have been applied to characterize the intermediate-range fluctuations near the metal-nonmetal transition in expanded liquid Hg. An analysis of voids acts as a useful adjunct to the normally discussed structural properties in interpreting the origin of intermediate-range fluctuations in the expanded liquids. The results for Hg-based and void-based partial pair distribution functions and the partial coordination number distributions reveal that the metallic domains (M domains) are built with packing of tetrahedral Hg 4   blocks. The M domains transform into the nonmetallic domains (NM domains) creating large voids (L voids) ～3.1 Å  in radius, which are supported by the network linked with tetrahedral Hg 4   blocks containing small voids (S voids) ～2.3 Å  in radius at densities of 9.2–10.5 g cm −3  , where the coordination number is rapidly reduced below six. The estimated density variations in S'cc (0)  from “domain model” and “void model” exhibit a peak around 10.5 g cm −3, which indicates that M domains and NM domains coexist near the metal-nonmetal transition region. There appears the prepeak at 0.8–1.2 Å −1 in the partial structure factor of L voids around the L voids, S'LV-LV (Q) , suggesting the chemical ordering of L voids. It follows that the intermediate-range concentration fluctuations resulting in microphase separation (clustering) of NM domains and M domains are reflected in the structural change near the metal-nonmetal transition.","subitem_description_type":"Abstract"}]},"item_5_publisher_7":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"American Physical Society"}]},"item_5_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1103/PhysRevB.80.014201","subitem_relation_type_select":"DOI"}}]},"item_5_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright(C) 2009 The American Physical Society"}]},"item_5_select_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"publisher"}]},"item_5_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11187113","subitem_source_identifier_type":"NCID"}]},"item_5_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"10980121","subitem_source_identifier_type":"ISSN"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Maruyama, Kenji"}],"nameIdentifiers":[{"nameIdentifier":"37493","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Endo, Hirohisa"}],"nameIdentifiers":[{"nameIdentifier":"37494","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hoshino, Hideoki"}],"nameIdentifiers":[{"nameIdentifier":"37495","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hensel, Friedrich"}],"nameIdentifiers":[{"nameIdentifier":"37496","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-07-29"}],"displaytype":"detail","filename":"80_1_014201.pdf","filesize":[{"value":"332.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"80_1_014201.pdf","url":"https://niigata-u.repo.nii.ac.jp/record/2502/files/80_1_014201.pdf"},"version_id":"2a20f704-f914-4743-bfa3-9865486fcf1b"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Void structure and intermediate-range fluctuations in the metal-nonmetal transition range in expanded liquid Hg","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Void structure and intermediate-range fluctuations in the metal-nonmetal transition range in expanded liquid Hg"},{"subitem_title":"Void structure and intermediate-range fluctuations in the metal-nonmetal transition range in expanded liquid Hg","subitem_title_language":"en"}]},"item_type_id":"5","owner":"1","path":["454","489"],"pubdate":{"attribute_name":"公開日","attribute_value":"2014-04-18"},"publish_date":"2014-04-18","publish_status":"0","recid":"2502","relation_version_is_last":true,"title":["Void structure and intermediate-range fluctuations in the metal-nonmetal transition range in expanded liquid Hg"],"weko_creator_id":"1","weko_shared_id":null},"updated":"2022-12-15T03:35:39.885903+00:00"}