@article{oai:niigata-u.repo.nii.ac.jp:00002502,
 author = {Maruyama, Kenji and Endo, Hirohisa and Hoshino, Hideoki and Hensel, Friedrich},
 issue = {1},
 journal = {Physical review. Third series. B, Condensed matter and materials physics, Physical review. Third series. B, Condensed matter and materials physics},
 month = {Jul},
 note = {The reverse Monte Carlo and Voronoi-Delaunay analyses have been applied to characterize the intermediate-range fluctuations near the metal-nonmetal transition in expanded liquid Hg. An analysis of voids acts as a useful adjunct to the normally discussed structural properties in interpreting the origin of intermediate-range fluctuations in the expanded liquids. The results for Hg-based and void-based partial pair distribution functions and the partial coordination number distributions reveal that the metallic domains (M domains) are built with packing of tetrahedral Hg 4   blocks. The M domains transform into the nonmetallic domains (NM domains) creating large voids (L voids) ～3.1 Å  in radius, which are supported by the network linked with tetrahedral Hg 4   blocks containing small voids (S voids) ～2.3 Å  in radius at densities of 9.2–10.5 g cm −3  , where the coordination number is rapidly reduced below six. The estimated density variations in S'cc (0)  from “domain model” and “void model” exhibit a peak around 10.5 g cm −3, which indicates that M domains and NM domains coexist near the metal-nonmetal transition region. There appears the prepeak at 0.8–1.2 Å −1 in the partial structure factor of L voids around the L voids, S'LV-LV (Q) , suggesting the chemical ordering of L voids. It follows that the intermediate-range concentration fluctuations resulting in microphase separation (clustering) of NM domains and M domains are reflected in the structural change near the metal-nonmetal transition.},
 pages = {014201-1--014201-10},
 title = {Void structure and intermediate-range fluctuations in the metal-nonmetal transition range in expanded liquid Hg},
 volume = {80},
 year = {2009}
}