@article{oai:niigata-u.repo.nii.ac.jp:00002233, author = {Tayama, Eiji and Orihara, Kiwako and Kimura, Hiroshi}, issue = {20}, journal = {Organic and Biomolecular Chemistry, Organic and Biomolecular Chemistry}, month = {Aug}, note = {The Stevens rearrangement of N-allylic α-aryl amino acid-derived ammonium salts and the Sommelet–Hauser rearrangement of N-benzylic α-alkyl amino acid-derived ammonium salts are shown to proceed with remarkably high levels of diastereoselectivity. The methods presented in this work provide new routes to optically active α-quaternary α-aryl amino acid derivatives.}, pages = {3673--3680}, title = {New synthetic routes to optically active α-quaternary α-aryl amino acid derivatives via the diastereoselective Stevens and Sommelet–Hauser rearrangements}, volume = {6}, year = {2008} }