@article{oai:niigata-u.repo.nii.ac.jp:00002010, author = {Tokue, Ikuo and Shimada, Hisanori and Masuda, Akemi and Ito, Yoshio}, issue = {7}, journal = {Journal of Chemical Physics, Journal of Chemical Physics}, month = {Oct}, note = {Fluorescence spectra of the Ã2Πu–X2Πg system of CO2+ and CS2+ ions, following electron impact on supersonic jet targets of CO2 and CS2, have been analyzed to determine vibrational populations. The vibrational distributions of the Ã2Πu state of CO2+ and CS2+ were found to be independent of the impact energy in the 30–300 eV range. The distribution of the CO2+ (Ã) state is very similar to the result obtained by He i photoelectron spectroscopy (PES), which is a Franck–Condon-type vertical ionization, whereas that of the CS2+ (Ã) state is significantly different from the PES data. This non-Franck–Condon behavior for formation of CS2+ (Ã) in the electron impact is discussed. The Journal of Chemical Physics is copyrighted by The American Institute of Physics.}, pages = {4812--4817}, title = {Vibrational distributions of the à 2Πu state of CO2+ and CS2+ produced by electron impact on jet-cooled CO2 and CS2}, volume = {93}, year = {1990} }