2024-03-29T15:27:34Z
https://niigata-u.repo.nii.ac.jp/oai
oai:niigata-u.repo.nii.ac.jp:00001552
2022-12-15T04:08:21Z
176:488:489
453:454
Copper(II)-salt-promoted oxidative ring-opening reactions of bicyclic cyclopropanol derivatives via radical pathways
Hasegawa, Eietsu
70
Tateyama, Minami
4252
Nagumo, Ryosuke
4253
Tayama, Eiji
4254
Iwamoto, Hajime
4255
copper(II) salt
cyclopropanol
electron transfer
free radical
radical ion probe
Copper(II)-salt-promoted oxidative ring-opening reactions of bicyclic cyclopropanol derivatives were investigated. The regioselectivities of these processes were found to be influenced by the structure of cyclopropanols as well as the counter anion of the copper(II) salts. A mechanism involving rearrangement reactions of radical intermediates and their competitive trapping by copper ions is proposed.
journal article
Beilstein Institut
2013-07
application/pdf
Beilstein Journal of Organic Chemistry
9
1397
1406
Beilstein Journal of Organic Chemistry
18605397
https://niigata-u.repo.nii.ac.jp/record/1552/files/9_1397-1406.pdf
eng
info:doi/10.3762/bjoc.9.156